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Question

Chemistry Question on Electrochemistry

Zinc displaces copper from copper sulphate solution. The E298KE^{\circ}_{298\, K} of ZnZn is 0.76V-0.76 \,V and that of CuCu is +0.34V+0.34 \,V.

A

If both assertion and reason are true and reason is the correct explanation of assertion

B

If both assertion and reason are true but reason is not the correct explanation of assertion

C

If assertion is true but reason is false

D

If both assertion and reason are false

Answer

If both assertion and reason are true and reason is the correct explanation of assertion

Explanation

Solution

Zn(s)+Cu2+(aq)>Zn2+(aq)+Cu(s) {Zn(s) + Cu^2+_{(aq)} -> Zn^2+_{(aq)} + Cu_{(s)}} ECu2+/Cu=0.34V,EZn/Zn=0.76VE_{Cu^{2+}/Cu}^{\circ}=0.34 V, E _{Zn/Zn}^{\circ}=-0.76 V Higher reduction potential of Cu ion than Zn ion shows that Cu ion has more tendency to undergo reduction.