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Question

Chemistry Question on p -Block Elements

Zinc and cold dil. HNO3 HNO_3 reacts to produce

A

NO

B

NO2N{{O}_{2}}

C

NH4NO3N{{H}_{4}}N{{O}_{3}}

D

ZnNO3ZnN{{O}_{3}}

Answer

NH4NO3N{{H}_{4}}N{{O}_{3}}

Explanation

Solution

CH3OHCH _{3} OH and C2H5OHC _{2} H _{5} OH can be differentiated by using Na2CO3Na _{2} CO _{3} and I2,C2H5OHI_{2}, C_{2} H_{5} O H gives yellow precipitate of CHI3C H I_{3} whereas CH3OHC H_{3} O H does not react with it.
C2H5OH+4I2+Na2CO3CHI3(yellow ppt.)lodoform+5NaI+HCOONa+3CO2+H2OC _{2} H _{5} OH +4 I _{2}+ Na _{2} CO _{3} \rightarrow \underset{\overset{\text{lodoform}}{\text{(yellow ppt.)}}}{CHI_3}+5 NaI + HCOONa +3 CO _{2}+ H _{2} O