Question
Question: Write the reaction products of \(2 - \)pentene when oxidized with acidified potassium permanganate a...
Write the reaction products of 2−pentene when oxidized with acidified potassium permanganate at 100∘C.
Solution
Dilute solutions of KMnO4 convert alkenes into acids. This behaviour is also used as a qualitative test for the presence of double or triple bonds in a molecule, since the reaction decolorizes the initially purple permanganate solution and generates a brown precipitate. It is sometimes called Baeyer’s reagent .
Complete answer: Baeyer's reagent is an alkaline solution of cold potassium permanganate of violet colour solution. It is a strong oxidizing agent. As this solution interacts with a double bond compound the colour disappears and becomes colourless.
Baeyer's reagent is a strong oxidizing reagent which is used to identify the presence of double or triple bonds in a hydrocarbon.
In this reaction, 2−pentene gets oxidized with acidified potassium permanganate and gives propanoic acid and ethanoic acid.
CH2CH2CH=CH2+4(O)+KMnO4→CH3CH2COOH+CH3COOH
Additional information:
Potassium permanganate is delivered industrially from manganese dioxide, which additionally happens as the mineral pyrolusite. In 2000,overall production was assessed at 30,000 tonnes. TheMnO2 is melded with potassium hydroxide and warmed in air or with another wellspring of oxygen, similar to potassium nitrate or potassium chlorate. This interaction gives potassium manganate:
2MnO2+4KOH+O2→2K2MnO4+2H2O
The potassium manganate is then converted into permanganate by electrolytic oxidation in alkaline media:
2KMnO4+2H2O→2KMnO4+2KOH+H2
Note:
Potassium permanganate does not dissolve in many organic solvents. It is soluble in acetone, water, pyridine, methanol and acetic acid. It is also readily soluble in inorganic solvents. It has a rich purple colour in concentrated solution and pink colour in diluted solution.