Question
Question: Write the common name and IUPAC name of the following. A.\(C{H_3}C{H_2}CHO\) B. \(C{H_3}COC{H_3}...
Write the common name and IUPAC name of the following.
A.CH3CH2CHO
B. CH3COCH3
C.
D. CH3COOH
E. HCHO
Solution
International Union of Pure and Applied Chemistry is abbreviated by IUPAC, standardizing nomenclature in chemistry, a set of rules to generate systematic names for chemical compound is one of the best known work for IUPAC. IUPAC is an international federation of National Adhering Organizations. Common names are what we use in our regular everyday life.
As we know that the above given compound contains single bonds and double bonds both in long carbon chains. To name this compound we will use IUPAC naming system, which is a predefined naming system for hydrocarbon compounds.
Complete step by step answer:
For acyclic compounds, the rules of IUPAC system of nomenclature:
First of all we see the number of chains lengths in the given compound. If the number of carbon atoms is one, then the compound named as meth−, for two carbon atoms, the compound is given as the name eth−, and for three, then called as prop−, etc.
Hydrocarbon chain type is saturated, unsaturated with one carbon-carbon double bond (C=C) or unsaturated with one carbon-carbon double bond (C≡C) are called −ane, −ene and −yne respectively. These are called primary suffixes. For example, methane, ethene and propyne.
Then we see the functional group present in the compound.
Alcohols(−OH): prefix: hydroxy−and suffix:−ol. For example:CH3CH2OH, name of the compound is ethanol and CH3OH, IUPAC name is methan ol.
Carboxylic acid (−COOH): prefix: carboxy- and suffix: -oic acid. For example: ethane dioic acid (COOH−COOH).
Ketone C=O: suffix: −one. For example: methan one,H2C=O.
Alphabetical order is first considered before the parent hydrocarbon without considering the presence of a functional group.
Carbon atoms contain a functional group itself (e.g., −CHO, −COOH, etc) are linked to carbon chain, such carbon should be also numbered.
For example, , the name of the compound is prop−1−ol.
Now we discuss about the compounds in the option as,
A.CH3CH2CHO
The given compound CH3CH2CHO contains three carbon atoms. For three carbon atoms the IUPAC name for the alkane is propane, because this is a saturated compound. Then we see if any functional group contains in the compound. The functional present in the compound is aldehyde.
Common name of the compound -propanaldehyde.
IUPAC name of the compound is propanal.
Now we discuss about option (B) as,
B.CH3COCH3
The molecular formula shows three carbon atoms present in the compound and then the functional group is ketone and the ketone is present in the second carbon. This is a saturated compound. So,
Common name of the compound is acetone.
IUPAC name of the compound is prop−2−one.
Let’s we see the option C as,
The given compound contains three carbon atoms. For three carbon atoms the IUPAC name for the alkane is propane, because this is not an unsaturated compound. Then we see if any functional group contains in the compound. The functional present in the compound is alcohol.
Common name of the compound is isopropyl alcohol.
IUPAC name of the compound is propan−2−ol.
4.CH3COOH
The above compound contains two carbon atoms, so the prefix is eth- and the functional group present in the compound is carboxylic acid.
Common name of the compound-acetic acid.
IUPAC name of the compound is ethanoic acid.
5.HCHO
The given compound HCHO contains two carbon atoms. For two carbon atoms the IUPAC name for the alkane is ethane, because this is a saturated compound. Then we see if any functional group contains in the compound. The functional present in the compound is aldehyde.
Common name of the compound -Formaldehyde.
IUPAC name of the compound is methanal
Note: IUPAC gives a unique name to every chemical compound. IUPAC, a non-governmental organization, many global issues involving the chemical sciences are addressed by IUPAC. IUPAC was established in 1919. IUPAC also published books, fields including chemistry, biology and physics. We have to remember for a variety of compounds there are predefined IUPAC nomenclature for the naming system. The process is almost the same of every compound. The variation in the naming can be due to different functional groups present in the chain and also due to presence of higher degree of compounds as a minor branch.