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Question: Why is ferric hydroxide colloid positively charged when prepared by adding ferric chloride to hot wa...

Why is ferric hydroxide colloid positively charged when prepared by adding ferric chloride to hot water ?

A

(a) Due to precipitations of ferric hydroxide there is an excess of Fe3+\mathrm { Fe } ^ { 3 + }ions.

A

(b) Due to preferential adsorptions of Fe3+\mathrm { Fe } ^ { 3 + } ions by the sol of Fe(OH)3\mathrm { Fe } ( \mathrm { OH } ) _ { 3 }.

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(c) Due to absence of absence of any negatively charged ion.

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(d) Due to adsorption of OH\mathrm { OH } ^ { - } and Cl\mathrm { Cl } ^ { - } ions, the remaining sol has only Fe3+\mathrm { Fe } ^ { 3 + }ions.

Explanation

Solution

(b)

Sol. The adsorption of positively charged Fe3+\mathrm { Fe } ^ { 3 + }ions by the sol of hydrated ferric oxide results in positively charged colloid.