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Question

Chemistry Question on Redox Reactions In Terms Of Electron Transfer Reactions

Why does the following reaction occur?
XeO64(aq)+2F(aq)+6H+(aq)XeO3(g)+F2(g)+3H2O(l)XeO_6^{4-}(aq) + 2F^ - (aq) + 6H^ + (aq) \rightarrow XeO_3(g) + F_2(g) + 3H_2O(l) What conclusion about the compound Na4XeO6Na_4XeO_6(of which XeO64XeO_6^{4-} is a part) can be drawn from the reaction.

Answer

The given reaction occurs because XeO64XeO_6^{4-} oxidises FF^- and FF^- reduces XeO64XeO_6^{4-}.

X+8eO64(aq)+2F+6H+XeO3(g)+F2(g)+3H2O(l)\overset{+8}{X}eO_6^{4-}(aq)+2F^-+6H^+\rightarrow XeO_3(g)+F_2(g)+3H_2O(l)

In this reaction, the oxidation number (O.N.) of XeXe decreases from +8+8 in XeO64XeO_6^{4- }to +6+6 in XeO3XeO_3 and the O.N. of FF increases from 1-1 in FF ^- to 00 in F2F_2.
Hence, we can conclude that Na4XeO6Na_4XeO_6 is a stronger oxidising agent than FF ^- .