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Question

Chemistry Question on coordination compounds

Which species does not exist?

A

(SiCl6)2{{(SiC{{l}_{6}})}^{2-}}

B

CCl62CCl_{6}^{2-}

C

GeCl62GeCl_{6}^{2-}

D

AlCl4AlCl_{4}^{-}

Answer

CCl62CCl_{6}^{2-}

Explanation

Solution

CCl62CCl_{6}^{2-} does not exist. The reason is that carbon has no d-orbital, hence it cannot combine with 6 chlorine-atoms. All others (Si, Ge and Al) have d-orbital, hence form the given ions.