Question
Question: Which out of the following is \[C{H_3}CO{O^ - }\] ion? A.Weak conjugate base B.Strong conjugate ...
Which out of the following is CH3COO− ion?
A.Weak conjugate base
B.Strong conjugate base
C.Weak conjugate acid
D.Strong conjugate acid
Solution
According to the Bronsted-Lowry protonic concept, acids are chemical compounds that are proton donors whereas bases are chemical compounds that are proton acceptors. The chemical compounds that behave as an acid or a base can be a molecule, a cation, or an anion.
Complete answer:
Step 1
According to Bronsted-Lowry, an acid-base reaction can be represented as
Acid ->Base + H+
Thus, we can say that acid and a base are related to each other. Every acid gets converted into a base after releasing a proton, and every base changes into acid after accepting a proton. So, all the acids and bases exist in pairs which are known as conjugate pairs. Therefore, the conjugate is a term for a chemical compound that differs from the other only due to a difference in the number of protons.
Step 2
According to this concept, neutralization is the process of transfer of a proton from the acid to its conjugate base.
Step 3
The acidic strength of an acid is determined by its tendency to lose a proton. Greater is the tendency of the acid to lose a proton, the stronger is the acid.
Step 4
The basic strength of a base is determined by its tendency to gain a proton. Greater is the tendency of the base to gain a proton, stronger is the base.
Step 5
The conjugate of a strong acid is always a weak base whereas the conjugate of a weak acid is always a strong base.
Step 6
Acetic acid is a weak acid which dissociates in water as follows:
C{H_3}COOH$$$$ + $$$${H_2}O->C{H_3}CO{O^ - }$$$$ + $$$${H_3}{O^ + }
The equilibrium constant for acetic acid in the given reaction is Ka=[CH3COOH][CH3COO−][H3O]=1.8×10−5.
The equilibrium constant for the acetate ion would be Keq=Ka1=[CH3COO−][H3O][CH3COOH]=5.5×104.
So, we can find that the conjugate base of a weak acid has a higher dissociation constant value so is a strong base.
Thus, we can see that acetate ion CH3COO−, the conjugate base of the weak acid, acetic acid CH3COOH is a strong base.
Hence, the correct option for the given question is option b).
Note: As per the Arrhenius concept an acid is a substance that gives H+ ion in aqueous solution while a base furnishes OH− ions in aqueous solution.