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Question: Which one of the following undergoes reaction with 50% sodium hydroxide solution to give the corresp...

Which one of the following undergoes reaction with 50% sodium hydroxide solution to give the corresponding alcohol and acid?

A

Phenol

B

Benzoic acid

C

Butanal

D

Benzaldehyde

Answer

Benzaldehyde

Explanation

Solution

Benzaldehyde undergoes disproportionation with 50% NaOH to given benzyl alcohol and sodium benzoate

C6H6CHO

C6H5CH2OH + C6H5COONa

This is Cannizzaro's reaction.