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Question

Chemistry Question on Solutions

Which one of the following salt will have the same value of vant Hoff's factor (i) as that of K4[Fe(CN)6]K_4[Fe(CN)_6] ?

A

Al2(SO4)3Al_2(SO_4)_3

B

NaCl

C

Al(NO3)3Al(NO_3)_3

D

Na2SO4.Na_2SO_4.

Answer

Al2(SO4)3Al_2(SO_4)_3

Explanation

Solution

Al2(SO4)3>2Al3++3SO42,i=5{ Al_2(SO_4)_3 -> 2Al^{3+} + 3SO^{2-}_{4}} ,i = 5
K4[Fe(CN)6]>4K+[Fe(CN)6]4,i=5{K_4[Fe(CN)_6] -> 4K^+ [Fe(CN)_6]^{4-} ,} i = 5
NaCl>Na++Cl,i=2{NaCl - > Na^+ + Cl^-,} i = 2
Al(NO3)3>Al3++3NO3,i=4{Al(NO_3)_3 -> Al^{3+} + 3NO^- _3,} i = 4
Na2SO4>2Na++SO42i=3{ Na_2 SO_4 - > 2Na^+ + SO_4^{2-} } i = 3