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Question

Chemistry Question on d -and f -Block Elements

Which one of the following metal ions is coloured ?

A

Cu+Cu^+

B

Zn2+Zn^{2+}

C

Sc3+Sc^{3+}

D

V4+V^{4+}

Answer

V4+V^{4+}

Explanation

Solution

Cu+:[Ar]183d10;Zn2+:[Ar]183d10Cu^+ : [Ar]^{18} \, 3d^{10} ; Zn^{2+} : [Ar]^{18} \, 3d^{10} Sc3+:[Ar]183d0;V4+:[Ar]183d1Sc^{3+} : [Ar]^{18} 3d^0 ; V^{4+} : [Ar]^{18} \, 3d^1 Out of these four ions only V4+V^{4+} is coloufed as all other ions have either d10d^{10} configuration or d0d^{0} configurationi.e., without any unpaired electron, since ions with one or more unpaired electrons are coloured.