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Question

Chemistry Question on Hydrocarbons

Which one of the following is NOT formed when a mixture of methyl bromide and bromo benzene is heated with sodium metal in the presence of dry ether ?

A

Ethane

B

Diphenyl

C

Propane

D

Toluene

Answer

Propane

Explanation

Solution

This is an example of Wurtz Fittig reaction .

CH3Brmethyl bromide+2na+BrCH3methyl bromide>[Ether]CH3CH3ethane+2NaBr\underset{\text{methyl bromide}}{{CH_3-Br}}+2na+\underset{\text{methyl bromide}}{{Br-CH_3}} { ->[{\text{Ether}}] } \underset{\text{ethane}}{{CH_3-CH_3}}+2NaBr

Propane cannot be prepared from this reaction .