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Question

Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

Which one of the following is most reactive towards electrophilic attack ?

A

B

C

D

Answer

Explanation

Solution

The group showing electron-donating effect (such as -NH2_2, -OH) should stabilise the intermediate ions, i.e. makes the ring more reactive towards electrophilic substitution than benzene and are called activating group while electron withdrawing group (such as -Cl,NO2Cl, NO_ 2) increases the positive charge on ring, thus deactivates the ring. Hence, phenol is more readily attacked by an electrophile