Question
Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques
Which one of the following is most reactive towards electrophilic attack ?
A
B
C
D
Answer
Explanation
Solution
The group showing electron-donating effect (such as -NH2, -OH) should stabilise the intermediate ions, i.e. makes the ring more reactive towards electrophilic substitution than benzene and are called activating group while electron withdrawing group (such as -Cl,NO2) increases the positive charge on ring, thus deactivates the ring. Hence, phenol is more readily attacked by an electrophile