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Question

Chemistry Question on coordination compounds

Which one of the following is expected to exhibit optical isomerism? (en = ethylenediamine)

A

Cis[R(NH3)2Cl2]Cis-[R(NH_3)_2Cl_2]

B

Trans[Co(en)2Cl2]+Trans - [Co(en)_2Cl_2]^+

C

Trans[R(NH3)2Cl2]Trans-[R(NH_3)_2Cl_2]

D

Cis[Co(en)2Cl2]+Cis-[Co(en)_2Cl_2]^+

Answer

Cis[Co(en)2Cl2]+Cis-[Co(en)_2Cl_2]^+

Explanation

Solution

Cis[Co(en)2Cl2]+Cis- [Co(en)_2 Cl_2 ]^+ is able to show the phenomenon of optical isomerism because it can form a superimposable mirror image.