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Question

Chemistry Question on Surface Chemistry

Which one of the following is an example for homogeneous catalysis?

A

Manufacture of ammonia by Haber's process

B

Manufacture of sulphuric acid by contact process

C

Hydrogenation of oil

D

Hydrolysis of sucrose in presence of dilute hydrochloric acid

Answer

Hydrolysis of sucrose in presence of dilute hydrochloric acid

Explanation

Solution

In homogeneous catalysis, reactants and catalyst are in the same phase. (a) SO2(g)+O2(g)Pt(s)SO3(g)SO _{2}(g)+ O _{2}(g) \stackrel{ Pt (s)}{\rightleftharpoons} SO _{3}(g) (Contact process) It is an example of heterogeneous catalysis. (b) N2(g)+H2(g)Fe(s)2NH3(g)N _{2}(g)+ H _{2}(g) \stackrel{ Fe (s)}{\rightleftharpoons} 2 NH _{3}(g) (Haber's process) It is an example of heterogeneous catalysis. (c) C12H22O11(aq)+H2O(aq)HCl(aq)C6H12O6C _{12} H _{22} O _{11}(a q)+ H _{2} O (a q) \stackrel{ HCl (a q)}{\rightleftharpoons} C _{6} H _{12} O _{6} +C6H12O6+ C _{6} H _{12} O _{6} It is an example of homogeneous catalysis. Oil(l)+H2(g)>[(Hardening)][Pt(s)]fat {Oil (l) +H_2(g) ->[{(Hardening)}][{Pt(s)}] fat} Thus, it is also an example of heterogeneous catalysis.