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Question

Chemistry Question on d block elements

Which one of the following is a diamagnetic ion ?

A

Co2+Co^{2+}

B

Cu2+Cu^{2+}

C

Mn2Mn^{2}+

D

Sc3+Sc^{3+}

Answer

Sc3+Sc^{3+}

Explanation

Solution

Co2+Co^{2+} (Z = 27) : [Ar]183d7[Ar]^{18}\, 3d^7 (3 unpaired electrons)
Cu2+Cu^{2+} (Z = 29) : [Ar]183d9[Ar]^{18} 3d^9 (1 unpaired electrons)
Mn2+Mn^{2+} (Z = 25): [Ar]183d5[Ar]^{18} \, 3d^5 (5 unpaired electrons)
Sc3+Sc^{3+} (Z = 21): [Ar]183d0[Ar]^{18} \, 3d^0 (No unpaired electron)
Sc3+Sc^{3+} with no unpaired electron will be diamagnetic