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Question

Chemistry Question on Hydrocarbons

Which one of the following gives only one monochloro derivative?

A

neoneo-Pentane

B

nn-Hexane

C

22-Methylpentane

D

33-Methylpentane

Answer

neoneo-Pentane

Explanation

Solution

neoneo-Pentane or 22, 22-dimethylpropane has only primary hydrogen hence it can give only monochloro derivative. All other compounds have 11^{\circ}, 22^{\circ} and 33^{\circ} hydrogens hence they give mono, di or trisubstituted products.