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Question

Chemistry Question on Amines

Which one of the following forms a green solid with nitrous acid?

A

Dimethylamine

B

Dimethylaniline

C

Methylamine

D

Methylaniline

Answer

Dimethylaniline

Explanation

Solution

Aromatic tertiary amines undergo electrophilic substitution with nitrosonium ion at p-position of the phenyl ring to form green coloured p-nitrosoamines.