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Question

Chemistry Question on Atomic Models

Which one of the following expressions represent the electron probability function ?

A

4πrdrψ24\,\pi \,r\,dr\,{{\psi }^{2}}

B

4πr2drψ4\,\pi \,{{r}^{2}}\,dr\,\psi

C

4πr2drψ24\,\pi \,{{r}^{2}}\,dr\,{{\psi }^{2}}

D

4πrdrψ4\,\pi \,r\,dr\,\psi

Answer

4πr2drψ24\,\pi \,{{r}^{2}}\,dr\,{{\psi }^{2}}

Explanation

Solution

The radial probability distribution of electron may be obtained by plotting the function 4 !!π!! 2r2Rn,l2\text{4}{{\text{ }\\!\\!\pi\\!\\!\text{ }}^{\text{2}}}{{\text{r}}^{\text{2}}}\text{R}_{\text{n,l}}^{\text{2}} against r, its distance from the nucleus. Such graphs are known as radial probability distribution curves. Similar curves are obtained if the complete wave function ψ\psi is taken in the expression 4π2R2.dr.4{{\pi }^{2}}{{R}^{2}}.dr. when the latter becomes 4π2r2ψ2dr.4{{\pi }^{2}}{{r}^{2}}{{\psi }^{2}}dr. So, the probability function σ=4πr2drψ2\sigma =4\pi {{r}^{2}}dr{{\psi }^{2}}