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Question

Chemistry Question on Thermodynamics

Which one of the following equations does not correctly represent the first law of thermodynamics for the given processes involving an ideal gas ? (Assume non-expansion work is zero)

A

Cyclic process : q=wq = - w

B

Isothermal process : q=wq = - w

C

Adiabatic process : ΔU=w\Delta U = - w

D

Isochoric process : ΔU=q\Delta U = q

Answer

Adiabatic process : ΔU=w\Delta U = - w

Explanation

Solution

For cyclic process : ΔU=0    q=w\Delta U = 0 \; \Rightarrow \; q = - w For isothermal process : ΔU=0    q=w\Delta U = 0 \; \Rightarrow \; q = - w For adiabatic process : q=0    ΔU=Wq = 0 \; \Rightarrow \; \Delta U = W For isochoric process : w=0    ΔU=qw = 0\; \Rightarrow \; \Delta U = q

So, the correct option is (C): Adiabatic process : ΔU=w\Delta U = - w