Question
Chemistry Question on Thermodynamics
Which one of the following equations does not correctly represent the first law of thermodynamics for the given processes involving an ideal gas ? (Assume non-expansion work is zero)
A
Cyclic process : q=−w
B
Isothermal process : q=−w
C
Adiabatic process : ΔU=−w
D
Isochoric process : ΔU=q
Answer
Adiabatic process : ΔU=−w
Explanation
Solution
For cyclic process : ΔU=0⇒q=−w For isothermal process : ΔU=0⇒q=−w For adiabatic process : q=0⇒ΔU=W For isochoric process : w=0⇒ΔU=q
So, the correct option is (C): Adiabatic process : ΔU=−w