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Question

Question: Which one of the following equations does not correctly represent the first law of thermodynamics fo...

Which one of the following equations does not correctly represent the first law of thermodynamics for the given process ?

A

Isothermal process : q = – w

B

Cyclic process : q = – w

C

Adiabatic process :Δ\DeltaE = q

D

Expansion of a gas into vacuum :Δ\DeltaE = q

Answer

Adiabatic process :Δ\DeltaE = q

Explanation

Solution

According to 1st law of thermodynamics,

Δ\DeltaE = q + w.

For isothermal process, Δ\DeltaE = 0. Hence, q = – w

For cyclic process, Δ\DeltaE= 0 Hence,

For expansion into vacuum, w = 0. hence Δ\DeltaE = q.