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Question

Chemistry Question on Group 15 Elements

Which one of the following elements does not form the compound, M4O10{{M}_{4}}{{O}_{10}} (M = element)?

A

P

B

Sb

C

Bi

D

As

Answer

Bi

Explanation

Solution

The stability of higher oxidation states decreases down the group due to inert pair effect. Hence, bismuth pentoxide which is obtained by the action of strong oxidizing agents on Bi2O3,B{{i}_{2}}{{O}_{3}}, is extremely unstable and loses oxygen to form trioxide. Therefore, BiBi does not form Bi4O10.B{{i}_{4}}{{O}_{10}}. .