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Question

Chemistry Question on Chemical Reactions

Which one of the following compounds forms a red coloured solution on treatment with neutral FeCl3\text{FeC}{{\text{l}}_{\text{3}}} solution ?

A

CH3COCH3C{{H}_{3}}COC{{H}_{3}}

B

CH3OCH3C{{H}_{3}}OC{{H}_{3}}

C

CH3CH2OHC{{H}_{3}}C{{H}_{2}}OH

D

CH3COOHC{{H}_{3}}COOH

Answer

CH3COOHC{{H}_{3}}COOH

Explanation

Solution

Acetic acid forms red coloured solution with neutral FeCl3.\text{FeC}{{\text{l}}_{\text{3}}}\text{.} Red colour is due to the formation of ferric acetate. 3CH3COOH+FeCl3(CH3COO)3FerricacetateFe3C{{H}_{3}}COOH+FeC{{l}_{3}}\xrightarrow{{}}\underset{\text{Ferric}\,\text{acetate}}{\mathop{{{(C{{H}_{3}}COO)}_{3}}}}\,Fe +3HCl+3HCl