Question
Question: Which one of the following complexes would exhibit the lowest value of paramagnetic behaviour?...
Which one of the following complexes would exhibit the lowest value of paramagnetic behaviour?
A
[Co(CN)6]3–
B
[Fe(CN)6]3–
C
[Mn(CN)6]3–
D
[Cr(CN)6]3–
Answer
Co(CN)63–
Explanation
Solution
[Co(CN)6]3– ;

n = 0
CN– is strong field ligand ; so it compels for pairing of electrons.