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Question: Which one of the following complexes would exhibit the lowest value of paramagnetic behaviour?...

Which one of the following complexes would exhibit the lowest value of paramagnetic behaviour?

A

[Co(CN)6]3–

B

[Fe(CN)6]3–

C

[Mn(CN)6]3–

D

[Cr(CN)6]3–

Answer

Co(CN)6Co(CN)63–

Explanation

Solution

[Co(CN)6]3– ;

n = 0

CN– is strong field ligand ; so it compels for pairing of electrons.