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Question

Chemistry Question on p -Block Elements

Which of the statements given below is incorrect ?

A

ONF is isoelectronic with O2NO_2 N^-

B

OF2OF_2 is an oxide of fluorine

C

Cl2O7Cl_2O_7 is an anhydride of perchloric acid

D

O3O_3 molecule is bent

Answer

OF2OF_2 is an oxide of fluorine

Explanation

Solution

i) No. of electron in ONF = 24
No. of electron in {NO_2^{-} = 24
both are isoelectronic
(ii) OF2{OF_2} is a fluoride of oxygen not oxide of fluorine because EN of fluorine is more than oxygen
OF2{OF_2} = oxygen difluoride
(iii) Cl2O7{Cl_2O_7} is an anhydride of perchloric acid
2HClO4>[Δ][H2O]Cl2O7{2HClO_4 ->[\Delta][-H_2O] Cl_2 O_7}
(iv) O3{O_3} molecule is bent