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Question

Chemistry Question on Hydrocarbons

Which of the following would not form upon electrolysis of aqueous solution of potassium propanoate?

A

Butane

B

Ethyl ethanoate

C

Ethyl propanoate

D

Ethene

Answer

Ethyl ethanoate

Explanation

Solution

CH3CH2COOKElectrolysisCH3CH2COOIC{{H}_{3}}C{{H}_{2}}COOK\xrightarrow[{}]{Electrolysis}\underset{I}{\mathop{C{{H}_{3}}C{{H}_{2}}CO{{O}^{\bullet }}}}\, CH3CH2II\xrightarrow[{}]{{}}\underset{II}{\mathop{CH_{3}^{\bullet }C{{H}_{2}}}}\, 2II2II\xrightarrow[{}]{{}} Butane; I+III+II\xrightarrow[{}]{{}} ethyl propanoate IIdisproportionationII\xrightarrow[{}]{disproportionation} ethene + ethane.