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Question

Chemistry Question on Alcohols, Phenols and Ethers

Which of the following will not give iodoform test ?

A

Ethanol

B

Ethanal

C

Isopropyl alcohol

D

Benzyl alcohol

Answer

Benzyl alcohol

Explanation

Solution

Any group having CH3COCH_3CO- group, along with ethanol and isopropyl alcohol would give iodoform test positive. This is because ethanol under reaction condition (oxidising) produces ethanal having CH3COCH_3CO- group. Also any secondary alcohol having CH3C(OH)CH_3-C-(OH)- group also produces a ketone having CH3COCH_3CO^- group on oxidation