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Question

Chemistry Question on Haloalkanes and Haloarenes

Which of the following will have the maximum dipole moment?

A

\ceCH3F\ce{CH3F }

B

\ceCH3Cl\ce{CH3Cl }

C

\ceCH3Br\ce{CH3Br }

D

\ceCH3I\ce{CH3I }

Answer

\ceCH3Cl\ce{CH3Cl }

Explanation

Solution

CH3Cl {CH_3Cl} has higher dipole moment than CH3F {CH_3F} due to much longer C-Cl bond length than the C-F bond. The much longer bond length of the C-C bond outweighs the effect produced by lower electronegativity of Cl than that of F.