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Question: Which of the following will have same value of van’t Hoff factor as that of \(K_{4}\lbrack Fe(CN)_{6...

Which of the following will have same value of van’t Hoff factor as that of K4[Fe(CN)6]?K_{4}\lbrack Fe(CN)_{6}\rbrack?

A

Al2(SO4)3Al_{2}(SO_{4})_{3}

B

AlCl3AlCl_{3}

C

Al(NO3)3Al(NO_{3})_{3}

D

Al(OH)3Al(OH)_{3}

Answer

Al2(SO4)3Al_{2}(SO_{4})_{3}

Explanation

Solution

K4[Fe(CN)6]4K++[Fe(CN)6]4K_{4}\lbrack Fe(CN)_{6}\rbrack \rightarrow 4K^{+} + \lbrack Fe(CN)_{6}\rbrack^{4 -}

Al2(SO4)32Al3++3SO42Al_{2}(SO_{4})_{3} \rightarrow 2Al^{3 +} + 3SO_{4}^{2 -}