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Question: Which of the following will act as cathode when connected to standard hydrogen electrode which has \...

Which of the following will act as cathode when connected to standard hydrogen electrode which has EoE^{o} value given as zero?

(i) Zn2+/Zn,Eo=0.76VZn^{2 +}/Zn,E^{o} = - 0.76V

(ii) Cu2+/Cu,Eo=+0.34VCu^{2 +}/Cu,E^{o} = + 0.34V

(iii) Al3+/Al,Eo=1.66VAl^{3 +}/Al,E^{o} = - 1.66V

(iv) Hg2+Hg,Eo=+0.885VHg^{2 +}Hg,E^{o} = + 0.885V

A

(i) and (ii)

B

(ii) and (iv)

C

(i) and (iii)

D

(i), (ii), (iii) and (iv)

Answer

(ii) and (iv)

Explanation

Solution

: When the value of standard reduction potential is positive, the electrode undergoes reduction and acts as cathode.