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Question

Chemistry Question on d -and f -Block Elements

Which of the following turns potassium dichromate paper green?

A

NO2N{{O}_{2}}

B

HClHCl

C

NH3N{{H}_{3}}

D

SO2S{{O}_{2}}

Answer

SO2S{{O}_{2}}

Explanation

Solution

SO2SO _{2} gas is a reducing agent, hence turns dichromate paper green due to formation of chromium sulphate. Sulphite radical (SO32)\left( SO _{3}^{2}\right) is identified by this. K2Cr2O7+3SO2+H2SO4Cr2(SO4)2green+K2SO4+H2OK_2Cr_2O_7 + 3SO_2 + H_2SO_4 \to \underset{\text{green}}{Cr_2(SO_4)_2} + K_2SO_4 + H_2O