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Question

Chemistry Question on d block elements

Which of the following turns potassium dichromate paper green?

A

NO2 NO_{2}

B

HClHCl

C

NH3 NH_{3}

D

SO2 SO_{2}

Answer

SO2 SO_{2}

Explanation

Solution

SO2SO _{2} gas is a reducing agent, hence turns dichromate paper green due to formation of chromium sulphate. Sulphite radical (SO32)\left( SO _{3}^{2-}\right) is identified by this:
K2Cr2O7+3SO2+H2SO4Cr2(SO4)2green+K2SO4+H2OK _{2} Cr _{2} O _{7}+3 SO _{2}+ H _{2} SO _{4} \longrightarrow \underset{\text{green}}{Cr _{2}\left( SO _{4}\right)_{2}} + K _{2} SO _{4}+ H _{2} O