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Question

Question: Which of the following transition element shows the highest oxidation state :...

Which of the following transition element shows the highest oxidation state :

A

Mn

B

Fe

C

V

D

Cr

Answer

Mn

Explanation

Solution

(I) [Cr(H2O)6]Cl3, x + 6(0) = +3 ; so x = +3 (II) CrO5 ,

; so x = +6

(III) K3[CrO8]3– or [Cr(O2)4]3–, here ligand is peroxo i.e. O22– ; x + 4 (–2) = –3 ; so x = +5.

(IV) (NH3)3CrO4 or [Cr(O2)2], here ligand is peroxo i.e. O22– ; x + 2 (–2) = 0 ; so x = +4.