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Question: Which of the following statements are correct regarding the halogens?...

Which of the following statements are correct regarding the halogens?

A

All halogens exist as diatomic gaseous molecules at ordinary temperature

B

Bromine dissolves in chloroform imparting blue colour

C

Chlorine monoxide is evolved when KClO3KClO_3 is treated with conc. H2SO4H_2SO_4

D

Chloride ion can be confirmed by chromyl chloride test

Answer

D

Explanation

Solution

The correct statements regarding halogens are evaluated below:

  • A: Incorrect. Br₂ is liquid, I₂ is solid at ordinary temperature.

  • B: Incorrect. Br₂ in CHCl₃ gives orange-brown color.

  • C: Incorrect. KClO3KClO_3 with conc. H2SO4H_2SO_4 evolves ClO2ClO_2, not Cl2OCl_2O.

  • D: Correct. Chromyl chloride test is a specific test for chloride ions, forming volatile orange-red CrO2Cl2CrO_2Cl_2 vapors.