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Question

Question: Which of the following statement is wrong ?...

Which of the following statement is wrong ?

A

The two sulphur atoms in the thiosulphate ions occupy equivalent positions

B

Ice results from cooling of water whereas snow results from cooling of vapours to solid

C

l2Formation of ice is solidification whereas formation of snow is Hoar frost

D

Ice sublimes on moon

Answer

The two sulphur atoms in the thiosulphate ions occupy equivalent positions

Explanation

Solution

1635S+SO32{}_{16}^{35}S + SO_{3}^{2 -} ¾® [1635SSO3]2\lbrack_{16}^{35}SSO_{3}\rbrack^{2 -} 2H+\overset{\quad 2H^{+}\quad}{\rightarrow} 1635S+H2O+SO2{}_{16}^{35}S + H_{2}O + SO_{2}The tagging technique confirms that two S atoms in S2O32– ions do not occupy equivalent positions.

Also, water solidification\overset{\quad solidification\quad}{\rightarrow} ice

ice sublation\overset{\rightarrow}{\quad subl芀ation\quad} vapour Hoarfrost\overset{\rightarrow}{\quad Hoarfrost\quad}ice

ice ¾® vapour

when ext. pressure is reduced on ice, Pext at moon = 0