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Question: Which of the following species are involved in the carbylamines test? (i) RNC (ii) \(\mathrm { CHCl...

Which of the following species are involved in the carbylamines test?

(i) RNC (ii) CHCl3\mathrm { CHCl } _ { 3 }

(iii) COCl2\mathrm { COCl } _ { 2 } (iv) NaNO2+HCl\mathrm { NaNO } _ { 2 } + \mathrm { HCl }

A

(i) and (iv)

B

(i) and (ii)

C

(ii) and (iv)

D

(ii) and (iii)

Answer

(i) and (ii)

Explanation

Solution

:

RNH2+CHCl3+3KOHΔRNC+3KCl+3H2O\mathrm { RNH } _ { 2 } + \mathrm { CHCl } _ { 3 } + 3 \mathrm { KOH } \xrightarrow { \Delta } \mathrm { RNC } + 3 \mathrm { KCl } + 3 \mathrm { H } _ { 2 } \mathrm { O } only RNC and CHCl3\mathrm { CHCl } _ { 3 } are involved in carbylamine reaction.