Question
Question: Which of the following sets of metals can form an alloy? (A) \( Cu \) and \( Au \) (B) \( Li \)...
Which of the following sets of metals can form an alloy?
(A) Cu and Au
(B) Li and Na
(C) Fe and Hg
(D) All of the above
Solution
Hint : It is observed that transition metals can form homogenous mixtures with one another in molten state. This homogenous mixture is known as alloy. Alloys are superior in physical properties of their parent metals.
Complete Step By Step Answer:
Copper Cu and gold Au are transition elements which have very similar atomic sizes and thus they can replace each other’s atom from the interstitial positions in their lattice; in this case replaces Cu some of the Au atoms in its lattice and thus forms a very stable compound which provides more strength and elasticity to Au . Only alloyed gold can be used to make jewelry as it is too soft.
It is chemically represented as Cu−Au,CuAu,Cu3Au, or auric cuprite.
Li And Na are alkali metals which have very high ionic character which are held by very strong lattice structure so there is very less chances of interstitial displacement hence they can’t form alloys.
Fe And Hg are both transition metals, and mercury Hg is known for its amalgamating compounds. Moreover, both these atoms are of the same size. Still they don’t form alloys because of the bond structure of Fe . Fe bonds are so strong that they don’t allow Hg atoms to diffuse into their lattice structure.
Option (A) is the correct option.
Additional Information:
Alloy formation between two or more metals changes the microstructure of the elements thereby bringing about physical as well as sometimes chemical differences in alloys from the pure metals.
Alloys generally improve strength and ductility of the material; improve malleability and toughness, alter the resistivity and other electrical properties, enhance the heat resistance and melting points and most importantly, build corrosion-resistant capability in metals.
Note :
Cu−Au alloy is stable and improves the hardness and toughness of pure gold. This gold can be used to make ornaments and used in other applications. Hence, gold ornaments’ purity depends upon the amount of Cu or Ag mixed in it. This is defined in carat value. 24 carat gold refers to 99% pure gold.