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Question

Chemistry Question on bond energies

Which of the following represents the lattice structure of A0.95OA _{0.95} O containing A2+,A3+A ^{2+}, A ^{3+} and O2O ^{2-} ions?Which of the following represents the lattice structure of A 095 O

A

A and B only

B

B and C only

C

A only

D

B only

Answer

A only

Explanation

Solution

Applying electrical neutrality principle in metal defficiency defect. 3A2+ are replaced by 2A3+, thus one vacant site per pair of A3+ is created

So, the correct option is (C): A only.