Question
Chemistry Question on Classification of elements & periodicity in properties
Which of the following represents the correct order of increasing first ionisation enthalpy for Ca,Ba,S,Se and Ar?
A
Ca<S<Ba<Se<Ar
B
S<Se<Ca<Ba<Ar
C
Ba<Ca<Se<S<Ar
D
Ca<Ba<S<Se<Ar
Answer
Ba<Ca<Se<S<Ar
Explanation
Solution
As we move down the group, the ionization enthalpy decreases. Consequently, the ionization energy of Ba<Ca and Se<S.
Generally, ionization energy increases from left to right within a period. Hence, S<Ar and Ca<Se.
Therefore, the correct sequence of increasing ionization enthalpies is option (C): Ba<Ca<Se<S<Ar.