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Question

Chemistry Question on Classification of elements & periodicity in properties

Which of the following represents the correct order of increasing first ionisation enthalpy for Ca,Ba,S,SeCa, Ba, S, Se and ArAr?

A

Ca<S<Ba<Se<ArCa < S < Ba < Se < Ar

B

S<Se<Ca<Ba<ArS< Se < Ca < Ba < Ar

C

Ba<Ca<Se<S<ArBa < Ca < Se < S < Ar

D

Ca<Ba<S<Se<ArCa < Ba < S < Se < Ar

Answer

Ba<Ca<Se<S<ArBa < Ca < Se < S < Ar

Explanation

Solution

As we move down the group, the ionization enthalpy decreases. Consequently, the ionization energy of Ba<CaBa < Ca and Se<SSe < S.
Generally, ionization energy increases from left to right within a period. Hence, S<ArS < Ar and Ca<SeCa < Se.

Therefore, the correct sequence of increasing ionization enthalpies is option (C): Ba<Ca<Se<S<ArBa < Ca < Se < S < Ar.