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Question

Chemistry Question on Surface Chemistry

Which of the following relation is correct? (i) xm=\frac{x}{m} = constant (at high pressure) (ii) xm=\frac{x}{m} = constant ×p1/n\times\, p^{1/n} (at intermediate pressure) (iii) xm=\frac{x}{m} = constant ×pn\times \,p^n (at lower pressure)

A

All are correct

B

All are wrong

C

(i) and (ii) are correct

D

(iii) is correct

Answer

(i) and (ii) are correct

Explanation

Solution

At lower pressure, the graph is nearly straight and sloping, i.e.,
xmp1\frac{x}{m} \propto p^1
or xm=\frac{x}{m} = constant ×p1\times p^1
At high pressure, xm\frac{x}{m} becomes independent of value of pressure.
xmp0\frac{x}{m} \propto p^0
or xm=\frac{x}{m} = constant
In the intermediate range of pressure, xm\frac{x}{m} will depend on pp raised to powers between 11 and 00, i.e., fractions.
xmp1n\frac{x}{m} \propto p^{\frac{1}{n}}
or xm=\frac{x}{m} = constant ×p1n\times p^{\frac{1}{n}}