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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following reagents converts both acetaldehyde and acetone to alkanes?

A

Ni/H2Ni/{{H}_{2}}

B

LiAlH4LiAl{{H}_{4}}

C

I2/NaOH{{I}_{2}}/NaOH

D

Zn-Hg/conc.HClZn\text{-}Hg/conc.HCl

Answer

Zn-Hg/conc.HClZn\text{-}Hg/conc.HCl

Explanation

Solution

Clemmensens reduction (conc. HCl/ZnHg)HCl/Zn-Hg) or Wolf-Kishner reduction (C2H5ONa/NH2NH2)({{C}_{2}}{{H}_{5}}ONa/N{{H}_{2}}N{{H}_{2}}) can be used to convert >C=O>C=O group into >CH2>C{{H}_{2}} group.