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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following reagents converts both acetaldehyde and acetone to alkanes?

A

Ni/H2 Ni/H_{2}

B

LiAlH4 LiAlH_{4}

C

I2/NaOHI_{2}/NaOH

D

ZnHg/conc.HClZn-Hg/conc.\,HCl

Answer

ZnHg/conc.HClZn-Hg/conc.\,HCl

Explanation

Solution

Clemmensen's reduction (conc. HCl/ZnHgHCl / Zn - Hg ) or Wolf-Kishner reduction (C2H5ONa/NH2NH2)\left( C _{2} H _{5} ONa / NH _{2} NH _{2}\right) can be used to convert >C=O> C = O group into >CH2> CH _{2} group.