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Question

Chemistry Question on Methods of Preparation of Haloalkanes

Which of the following reacts with both acetaldehyde and acetone?

A

F.S

B

CH3MgBrCH_{3}MgBr

C

T.R

D

Benedict solution

Answer

CH3MgBrCH_{3}MgBr

Explanation

Solution

Grignard's reagent reacts with aldehydes and ketones both. Aldehydes give secondary alcohol (formaldehyde gives 11^{\circ} alcohol) while ketones give tertiary alcohols with Grignard's reagent. e.g.,