Question
Question: Which of the following reactions is non-stereospecific but stereoselective? \[A)S{N_1} \\\ B){...
Which of the following reactions is non-stereospecific but stereoselective?
B){E_1} \\\ C){E_2} \\\ D){E_1}cB $$Solution
Hint : A stereospecific mechanism specifies the stereochemical outcome of a given reactant, whereas a stereoselective reaction selects products from those made available by the same, non-specific mechanism acting on a given reactant of stereoisomeric reactants, each behaves in its own specific way.
Complete Step By Step Answer:
The main difference between stereospecific and stereoselective reactions is that a stereospecific reaction gives one specific product whereas stereoselective reaction gives multiple products.
A E1 reaction involves the deprotonation of a hydrogen nearby the carbocation resulting in the formation of an alkene product. In order to accomplish this, a Lewis base is required. It is a type of organic reaction in which two substituents are removed from a molecule in either a one- or two-step mechanism
The one-step mechanism is known as the E2 reaction, and the two-step mechanism is known as the E1 reaction. The numbers refer not to the number of steps in the mechanism, but rather to the kinetics of the reaction. E2 Is bimolecular while E1 is unimolecular. Elimination may be considered the reverse of an additional reaction.
It is a two-step process of elimination: ionization and deprotonation. Ionization the carbon-halogen bond breaks to give a carbocation intermediate. Deprotonation of the carbocation.
So, the correct answer is B)E1 .
Note :
There are competitions between E2 and SN2 and also between E1 and SN1 . Substitution generally predominates and elimination occurs only during precise circumstances. Generally, elimination is favored over substitution when steric hindrance around the α− carbon increases, a stronger base is used, temperature increases and when the base is a poor nucleophile. Bases with steric bulk are often poor nucleophiles.