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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

Which of the following reactions involves carbon-carbon bond formation

A

Reimer-Tiemann reaction

B

Hydroboration oxidation

C

Cannizzaro reaction

D

Reaction of primary alcohol with PCC

Answer

Reimer-Tiemann reaction

Explanation

Solution

Ortho-para directing groups activate the benzene ring towards electrophilic substitution while meta directing groups deactivate the benzene nucleus towards electrophilic substitution. ??,??l,??r??,??l,??r and ???? (i.e., halogens) are exceptions to the above rule. These groups are o,po-, p -directing but deactive the benzene ring