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Question

Chemistry Question on d block elements

Which of the following pair is expected to exhibit same colour in solution?

A

VOCI2;FeCI2VOCI_2; FeCI_2

B

CuCI2;VOCI2CuCI_2;VOCI_2

C

MnCI2;FeCI2MnCI_2;FeCI_2

D

FeCI2;CuCI2FeCI_2;CuCI_2

Answer

CuCI2;VOCI2CuCI_2;VOCI_2

Explanation

Solution

In CuCl2_2, Cu2_2 has d9d^9- configuration, exhibit d-d transition and show colour. Similarly in VOCl2,V4+hasd1_2, V^{4+} \, has \, d^1 configuration, car exhibit d-d transition and show colour.