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Question

Chemistry Question on Oxygen

Which of the following oxides of chlorine is obtained by passing dry iodine over silver perchlorate at 190C190{}^\circ C ?

A

Cl2OC{{l}_{2}}O

B

ClO2Cl{{O}_{2}}

C

ClO3Cl{{O}_{3}}

D

ClO4Cl{{O}_{4}}

Answer

ClO4Cl{{O}_{4}}

Explanation

Solution

Chlorine tetroxide (ClO4)(Cl{{O}_{4}}) is obtained, when 12 is treated with an etheral solution of AgClO4AgCl{{O}_{4}} (silver perchlorate). 2AgClO4+I2AgI+2ClO42AgCl{{O}_{4}}+{{I}_{2}}\xrightarrow{{}}AgI\downarrow +2Cl{{O}_{4}}