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Question

Chemistry Question on Modern Periodic Law And The Present Form Of The Periodic Table

Which of the following order is wrong?

A

NH3<PH3<AsH3NH _{3}< PH _{3}< AsH _{3}- Acidic

B

Li<Be<B<CLi < Be < B < C - First IPIP

C

Al2O3<MgO<Na2O<K2OAl _{2} O _{3}< MgO < Na _{2} O < K _{2} O - Basic

D

Li+<Na+<K+<Cs+Li ^{+}< Na ^{+}< K ^{+}< Cs ^{+}-ionic radius

Answer

Li<Be<B<CLi < Be < B < C - First IPIP

Explanation

Solution

Li1s22s1;Be1s22s2;B1s22s22p1;C1s22s22p2Li \rightarrow 1 s ^{2} 2 s ^{1} ; Be \rightarrow 1 s ^{2} 2 s ^{2} ; B \rightarrow 1 s ^{2} 2 s ^{2} 2 p ^{1} ; C \rightarrow 1 s ^{2} 2 s ^{2} 2 p ^{2}
Li<B<Be<CLi < B < Be < C
BeBe is having higher ionisation potential than BB as BeBe is having fully filled 2s2 s - orbital due to which it gets extra stability.