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Question

Chemistry Question on Dipole moment

Which of the following molecules has "NON ZERO" dipole moment value?

A

CCl4

B

HI

C

CO2

D

BF3

Answer

HI

Explanation

Solution

A molecule has a non-zero dipole moment when there is a separation of charge due to differences in electronegativity between the bonded atoms and the molecule's geometry does not lead to cancellation of these individual bond dipoles.

CCl 4: Carbon tetrachloride has a tetrahedral geometry. Although the C-Cl bonds are polar, the symmetrical arrangement of the four chlorine atoms around the central carbon atom leads to the cancellation of the bond dipoles, resulting in a net zero dipole moment.

HI: Hydrogen iodide is a diatomic molecule. Iodine is more electronegative than hydro- gen, creating a polar bond and a net dipole moment pointing towards the iodine atom. Because it's diatomic, there are no other bond dipoles to cancel it out.

CO 2: Carbon dioxide has a linear geometry. The C=O bond s are polar, but the molecule's symmetry results in the cancellation of the bond dipoles, leading to a zero net dipole moment.

BF 3: Boron trifluoride has a trigonal planar geometry. The B-F bonds are polar, but their symmetrical arrangement around the central boron atom results in the cancellation of the bond dipoles, leading to a net zero dipole moment.