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Question: Which of the following is/are correct regarding the distribution of speed of N<sub>2</sub> and CO<su...

Which of the following is/are correct regarding the distribution of speed of N2 and CO2 at the definite temperature ?

A

B

C

D

Answer

Explanation

Solution

umps = 2RTM\sqrt{\frac{2RT}{M}} ; hence as M increases umps decreases

\(umps)N2(u_{mps})_{N_{2}}> (umps)CO2(u_{mps})_{CO_{2}}

1 N\frac { 1 } { \mathrm {~N} } dNudu\frac{dN_{u}}{du} = 4p (M2πRT)3/2\left( \frac{M}{2\pi RT} \right)^{3/2} × u2 eMu2/2RTe^{- Mu^{2}/2RT}

At u = umps

1 N\frac { 1 } { \mathrm {~N} } dNudu\frac{dN_{u}}{du} = 4p (M2πRT)3/2\left( \frac{M}{2\pi RT} \right)^{3/2}× 2RTM\frac{2RT}{M} × e–1

At the definite temp and at u = umps

1 N\frac { 1 } { \mathrm {~N} } dNudu\frac{dN_{u}}{du} µ M\sqrt{M}

Higher the value of M, greater will be the height of maxima.

\ At u = umps , For CO2 (1NdNudu)\left( \frac{1}{N}\frac{dN_{u}}{du} \right) is greater.